Tetrakis(μ-4-azidobenzoato-κ2 O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
نویسنده
چکیده
The binuclear title compound, [Cu(2)(C(7)H(4)N(3)O(2))(4)(C(3)H(7)NO)(2)], is a discrete metal-organic compound having a paddle-wheel-type structure. The Cu⋯Cu distance is 2.6366 (5) Å and an inversion center is located at the mid-point of this bond. The Cu(II) cation is coordinated by four carboxyl-ate O atoms from four 4-azido-benzoate ligands, and one O atom from a dimethyl-formamide mol-ecule, forming an overall distorted octahedral geometry when the Cu⋯Cu bond is also considered.
منابع مشابه
Tetrakis(μ-naphthalene-1-acetato-κ2 O:O′)bis[(N,N-dimethylformamide-κO)copper(II)]
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)O(2))(4)(C(3)H(7)NO)(2)], contains two independent centrosymmetric dinuclear copper(II) complexes. The central paddle-wheel units are formed by four bridging bidentate naphthalene-1-acetate ligands with two dimethyl-formamide ligands in the axial positions. The unique Cu(II) ions have slightly distorted square-pyramidal coordination geo...
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